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Low carbon sustainable concrete

Concrete is the most-used manufactured substance on the planet in terms of volume. It is used to build homes, schools, hospitals, workplaces, roads, railways and ports, and to create infrastructure to provide clean water, sanitation and energy [1]. Concrete is manufactured by mixing cement, water, aggregates and small quantities of chemical admixtures to improve its properties and meet specific product requirements. The direct CO2 emissions related to concrete largely come from cement production. The cement used today, called Ordinary Portland cement (OPC), is made from finely ground Portland clinker and gypsum. Clinker is produced by heating crushed limestone, clay and sand to 1450 °C [2]. Within the clinker production, there are two main sources of CO2: direct emissions (60%) stemming from the decarbonation of limestone and indirect emissions (40%) from burning fuel [3]. The European cement industry has actively worked on reducing emissions for a long time. In 2013, CEMBUREAU elaborated a Roadmap, which was revised in 2018 to ensure the objective of carbon neutrality down the cement and concrete value chain set for 2050 are met. A schematic illustration of 2050 road map is shown in Figure 1 [2]. 

Figure 1. CEMBUREAU 2050 roadmap. CO2 reductions along the cement value chain (5Cs: clinker, cement,  concrete, construction, re-carbonation) Source: Cembureau [2]

 

SUSTAINABILITY  

 

OPC typically contains 95% clinker and 5% gypsum. A very effective strategy of reducing cement footprint is to substitute part of the Portland clinker with other materials for which the footprint is low or even zero. Such substitutes are called supplementary cementitious materials (SCMs) and include: granulated blast furnace slag (GBFS), a by-product of pig-iron production in blast furnaces, fly ash (FA), a by-product from coal-fired power plants, natural pozzolanic materials obtained from volcanic compounds, sedimentary rocks (limestone), clays, agricultural residues (rice husk ash), silica fume (a by-product of silica and ferro-silica alloy production processes) and mixes thereof [3,4,5]. OPC clinkers partially substituted with one or more SCMs are referred to as blended cements. Reducing the clinker content in cement saves both energy-related and embodied CO2 [3]. Examples of projects applying this concept are LC3 and EnDurCrete

 

INNOVATION/NEW MATERIALS 

 

Alternatives to Portland cement can achieve significant emission savings as they rely on different raw material mixes and require lower firing temperatures. Belite-rich Portland clinkers are produced with the same process as OPC clinkers, but with less limestone in the clinker raw material mix, thus the CO2 generation is reduced. However, this emission reduction of around 10% is rather modest relative to OPC [3].  

 

A promising lower-carbon alternative is calcium sulphoaluminate (CSA) clinker. It contains ye’elimite as the main constituent, which reduces direct CO2 emissions by 44% [1]. Unfortunately, their cost also increases significantly at the same time, because higher ye’elimite content requires more expensive aluminium-rich raw materials [3]. Belite calcium sulphoaluminate (BCSA) clinker is able to circumvent the high raw material costs of CSA clinkers. They are preferably referred to as “belite–ye'elimite–ferrite” (BYF) cements. Such clinkers have CO2 savings of 20% or greater per unit of clinker in the cement due to the lower limestone content with additional savings coming from the lower firing temperatures and 30-50% lower electricity demand for grinding as they are more friable [1]. Projects applying and developing these new types of materials include Ecobinder for BYF cements. Commercially available BYF clinkers Aether and Ternocem have the potential to replace OPC clinker in many major applications [3].  

 

The carbonated calcium silicates (CACS) clinkers, primarily consist of wollastonite cured with CO2. Process CO2 emissions generated in CACS clinker making are, in principle, re-absorbed during the CO2 curing process [1]. Solidia cements (Solid life) have recently been commercialised for fabricating certain cement-based products, but the CO2 gas for curing currently comes from industrial gas suppliers. The long-term goal is to use recycled industrial CO2 from industrial flue gases, promoting emission reductions and circularity [3]. 

 

Cements based on magnesium oxides derived from magnesium silicates (MOMSs) are able to counterbalance and absorb the CO2 released in the manufacturing process while curing. If the magnesium oxides are coming from natural magnesium sources free of carbon, such as magnesium silicate rocks, they would yield net negative CO2 emissions, having a true environmental advantage [1]. CO2MIN is a good example, focusing on identifying such rocks. 

Figure 2. CO2 savings with LC3 cement  Source: LC3 [11] 

 

RECYCLING and RE-CARBONATION 

Concrete reabsorbs a significant amount of CO2 over its normal service lifetime and also after demolition. The recarbonation of recycled cement paste is a rapid process at normal pressure and temperature, showing a substantial CO2 sequestration potential. This concept reduces the CO2 footprint of cement, promotes recycling of end-of-life concrete and circularity as the carbonated material can be used as SCM for the production of new blended cements [2]. Examples of projects applying and developing recycling technologies are C2CA, TRACK4REUSE and RE4

 

Users of such solutions can be:  

-Industries, universities and research institutions investigating durability, sustainability, alternative cement materials, recycling and re-carbonation along concrete value chain 

-Potential customers in the target sectors: concrete markets and manufacturers of new concrete technologies  

-Recommendations and standardisation experts

Figure 3. Direct(=process) CO2 emissions generation intensity for selected clinkers. Source: IEA [1] 

 

MATURITY:  

 

Several solutions for low carbon concrete are already ready for commercial deployment or available on the market, for example: 

  • LC3 is a technology that is market-ready and it is already produced in several plants in the world [11] 

  • Aether has been demonstrated in two industrial trials completed in 2012 with 10,000t of Aether clinker produced [12]. Since 2014 customer testing is ongoing [13]. It is not commercially produced yet because specific norms for this type of clinkers do not exist, with the exception of China that has normalised their use in construction for more than 30 years [1]. 

  • Solidia cement has been successfully produced in two continents and Solidia concrete has been successfully demonstrated in 10 countries worldwide [14]. 

 

Solutions are in demonstration include: 

  • Carbon8 has been demonstrated at scale [15] 

  • FastCarb produced two demonstrators for concrete walls formulated using recarbonated recycled aggregates [16]. 

  • EnDurCrete tested full-scale demonstrator in four different locations in Europe, in working sites of tunnels and ports (Spain), bridges (Croatia) and offshore structures (Norway). After project completion, a time-to-market of 3-4 years is expected [17]. 

In this collection

Grey water treatment (including Nature Based Solutions) and reuse

Greywater is the wastewater generated in households or office buildings without serious contaminants, such as water from baths, sinks and washing machines. Greywater can be separated from blackwater (water from toilets or kitchens) and then treated on-site for direct reuse in toilets recharge or irrigation. Greywater is a relevant secondary source of water and nutrients. Many studies have analysed the environmental, economic, and energetic benefits of the reuse of greywater [1][2][6][7]. Greywater treatment systems can be introduced in new buildings or in existing buildings with retrofitting measures. There are different greywater treatment systems: diversion and filtration, diversion and treatment (using chemicals), or nature-based solutions (NBS). 

 

Traditional greywater treatment 

Greywater treatment by mechanical systems is typically based on filtration or treatment with chemicals. In filtration, the aim is to remove impurities using filters, with typically a few or several filters in a row in order to guarantee good results. In a purifying process done with chemicals, the aim is to add chemicals that bind impurities, which are then removed from the water, for example, by filters. The mechanical treatment can start with a settlement tank, where coarse particles settle in the bottom of the tank and are then removed. After that, the greywater flows through filters, typically first gravel and sand and then biological filters like wood or peat. Last, if needed, ultraviolet light or chemicals are used to remove potential bacteria. 

Green roof and greywater treatment [7] 

 

Grey water recovery system [10] 

The first filter is a biofilter, which removes the fats and oil. The sand and gravel filter removes small particulates and other impurities. 

 

NBS-based greywater treatment 

Nature-based solutions (NBS) applications are typically constructed wetlands, green roofs, and green walls [1][2][3]. 

 

Several studies have shown that NBS-based greywater treatment has high removal performances [1][5], indicating the suitability of these systems in treating domestic greywater. Planning and design parameters should be carefully considered when implementing NBS; high residence time of water can be especially important for grey water treatment efficiency (see e.g., [1]). To optimize the removal processes in NBS, appropriate plant species and substrates (as growing material), optimal hydraulic parameters, and suitable operating conditions are needed.  

 

The decentralized process consists of several stages: (i) greywater separation, (ii) storage, (iii) treatment by innovative NBS as multi-level green walls/green façades, or by mechanical systems as multi-layer filters and activated carbon, and (iv) final disinfection using commercial O3/UV systems (Ozone and Ultraviolet).  

MATURITY:  

 

Some building-level solutions for grey water treatment and reuse (including nature-based) are commercially available, for example:  

 

  • Aqua Gratis is a technology to capture and reuse the bath and shower water for flushing toilets. The solution is at the stage of initial market commercialisation. The technology development of Aqua Gratis was funded by the EU

  • REDI gives a solution for single-family houses, where the treated greywater can be used for watering the garden. 

  • Disinfection can be done with commercially available solutions, e.g. with ozone and ultraviolet (UV) light. 

 

Some examples of pilots are: 

 

  • Greywater treatment with nature-based solutions for indoor or outdoor modules in multi-level green walls/green façades was carried out in Houseful. The project tested also ozone and ultraviolet light for disinfection.  

  • Water management systems and how to monitor and collect water condition information for urban water management platforms were piloted in UNaLab. 

  • Green walls and constructed wetlands were piloted in NAWAMED, with a focus on grey water treatment from a public building, a parking area, and a refugee camp. 

  • A service model for grey water treatment with NBS was tested in Houseful. The service model considers a leasing contract and a payment fee per m3 of water treated and reused. 

 

The nature-based grey water systems have been tested in a rather short period of time (e.g., some months to 1–2 years). Since the operating time of grey water treatment should be closer to 15-20 years, a further full-scale testing is still needed. [1]. 

Passive building design strategies: building orientation, passive heating and cooling

Passive building design means providing passive heating, passive cooling, and natural ventilation to maintain comfortable indoor conditions with no need for energy, by taking advantage of location (climate), orientation, massing, shading, material selection, thermal mass, insulation, internal layout and the positioning of openings to allow the penetration of solar radiation, daylight, and ventilation in the desired amounts [1–8]. When duly applied, passive design strategies are a designer’s first opportunity to increase a building’s energy efficiency, without adding much less front-end cost to a project as compared to active design strategies. Efficient passive design results in smaller heating and cooling loads (so that the building’s mechanical system – if any – can be downsized) and smaller electric loads for lighting through the use of daylighting design strategies.  

 

Beyond local climate, building orientation is a key aspect for passive design. The most energy-efficient designs are facing south or north to allow better solar energy management and better quality of daylighting. Building shape is also very relevant in the design, as an elongated and narrow plant (with south or north facing façade) allows for more of the building to be receive daylight. Shading strategies properly combined with other passive design strategies are also required, especially in hot climates [9,10]. Since the main difficulty in designing natural ventilation systems driven by buoyancy and wind is the simultaneous estimation of ventilation airflows and indoor temperatures, solar chimneys are used [11,12]. A solar chimney is a vertical shaft utilizing solar energy to enhance natural ventilation. 

 

Passive heating can be achieved by capturing the heat from the sun inside the building. Tweaking the window-to-wall ratio and the building exposure to the sun, all the while controlling for the thermal mass, heat flows and insulation allows to effectively store, distribute and retain the heat. The thermal mass defines the capacity to absorb, store and release heat. Heavyweight construction materials like concrete, brick and stone exhibit large thermal mass that can be used to effectively store the heat over peak hours and release it overnight. 

Passive building design. Figure from

 

Passive cooling is a set of design strategies to reduce heat gains and favour heat dispersion. Many methods exist and include using solar shadings as well as designing openings in such a way to allow good ventilation (such as solar chimneys). Shading can either be operable (external louvres, blinds, and deciduous trees) or fixed (e.g. eaves, overhangs, fences and evergreen trees). 

 

 '

Shading devices for north-facing openings. 

Figure from https://www.yourhome.gov.au/passive-design 

 

Passive design strategies are rated in different standards, such as PassivHaus (Passive House), BREEAM, LEED or WELL. 

 

The literature shows that today there are many net-zero, nearly-zero energy, and certified Passive House buildings worldwide, in different climate or geographic regions. Most are in Europe and North America, followed by New Zealand, Kore, Japan, China, and India [1]. Literature also shows that is it possible to achieve at least the Passive House energy standard of performance in all climate zones [13]

 

MATURITY:  

 

Although individual passive techniques are already commercial, their holistic implementation in buildings is still at TRL=4-6. 

Citizen Participation Platforms

E-participation [1][2][3][4][5] enables citizens to use digital technologies or platforms, e.g., combination of geographic information systems (GIS), Web 2.0 and mobile technologies (including video, mobile messaging and Internet access), for communication, engagement and deliberation on policy or planning challenges.  

 

Engagement and participation are vital tools in climate adaptation and environmental decision making as these entail increased community acceptance, support for climate actions, and provide new insights based on local knowledge [12]. Citizens can be consumers as well as producers of useful data for policy development and decision making (WeGovNow, Smarticipate, AI4PublicPolicy). 

 

There are multiple degrees of citizen participation ranging from passive, i.e., being simply informed, to responsive, i.e., contribute to consultation, to active, i.e., being fully empowered by having final decisions delegated to them (see Arnstein’s ladder [6]) [7]. In e-participation initiatives, both top-down (i.e., issues identified by public authority) and bottom-up (i.e., citizens led initiative) approaches can be applied. As multiple actors (i.e., different departmental units) are involved in the provision of e-participation, cross-organizational issues related to ownership and accountability may arise [3].  

 

Technologies supporting government processes (GovTech) can add great value to participatory processes (e.g., access to sensor kits, web portals and data), as shown by examples of Madrid (Decide Madrid), Bristol (Bristol Approach to citizen sensing e.g., air quality, solid fuel burning etc.) [7], and Brussels (Curieuzenair). E-participation is usually considered part of e-government [5]. 

 

E-Government (or Electronic-Government) [1][2][8] refers to the application of Information and Communication Technologies (ICT) to government functions and procedures with the objective to increase efficiency of government agencies, enhance delivery of public services, and facilitate low cost and faster public engagement with public authorities. A comparative survey [8] of global e-government performance of municipalities highlights the best e-governance practices. It uses five categories of measures: privacy and security, usability, content, service and citizen and social engagement. For citizen and social engagement category Shanghai, Auckland, Seoul, Madrid, Paris, and Lisbon are ranked top cities for year 2018-19. 

 

Open Governance [9] is about transparency of and access to government data and decision making process so that innovative forms of collaborative actions (i.e. bottom-up and top-down) can be applied to solve policy problems, raise awareness, increase public participation, change behaviour, promote e-democracy, and revolutionise traditional service provision [10][11]. It is closely associated with open government data that can provide new insights about issues and services as well as offers the opportunities to participate, comment and influence plans and policy agenda to foster greater citizen participation. 

 

 

E-participation solutions range from responding to planning e.g., top-down to bottom-up urban regeneration [Smarticipate] or policy challenge [WeGovNow] or reporting a local problem (e.g., Bristol’s FixMyStreet); or bottom-up budget planning (e.g., Helsinki’s participatory budgeting) or accessing open data (e.g., Hamburg’s Transparency portal).  

 

There are several e-participation initiatives where various ICT tools are used to deliver different public services. For instance,  

Cross border e-governance initiatives such as [ACROSS], [DE4A] and [GLASS] go beyond one city’s public administrative level (even at EU level and beyond [iKaaS]) and deal with cross-border interoperable, mobile [mGov4EU] and privacy-aware public services.  

MATURITY: 

 

Many e-government and e-participation tools are available at higher TRL and are already being used by municipalities for public services and e-participation, e.g., open source Consul platform is being used in 35 countries by 135 institutions; Similarly, Organicity tools are used for over 35 experiments in various cities

 

Some of the example solutions fall under validation and demonstration category such as DUET and Smarticipate.  

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